Unlocking the sustainable potential of 3D concrete printing with large aggregates and steam–CO2 curing
 
 Three-dimensional concrete printing (3DCP) has emerged as a promising innovation in the construction industry, significantly reducing its reliance on intensive labor while minimizing material waste. Despite its benefits, a major limitation of current 3DCP practices is the high reliance on cement as the primary binder, which often exceeds 60% of the total solid content. This high cement usage contributes significantly to CO2 emissions, raising sustainability concerns. In this study, a 3D-printable concrete mix incorporating large aggregates (up to 10 mm) was developed, replacing over 7% of fine aggregate and reducing cement content to approximately 29% by weight. The effects of CO2 gas and a steam–CO2 mixture on the mechanical performance and CO2 uptake of the printed concrete were assessed. Thermogravimetric analysis was used to quantify CO2 sequestration over time. Compared to control samples without gas treatment, those exposed to the steam–CO2 mixture showed enhanced buildability, improved compressive and flexural strength, and greater CO2 uptake. The results suggest that surface spraying of the steam–CO2 mixture during the 3D printing process offers a viable and scalable approach to improving both the structural performance and environmental footprint of printed concrete elements.

- Pongwisuthiruchte A, Potiyaraj P. Challenges and innovations in sustainable 3D printing. Mater Today Sustain. 2025;31:101134. doi: 10.1016/j.mtsust.2025.101134
- Available from: https://builtin.com/articles/3d-printed-house [Last accessed on 2025 Jun 04].
- Jia Y, Abdelrahman S, Hauser CA. Developing a sustainable resin for 3D printing in coral restoration. MSAM. 2024;3(2):3125. doi: 10.36922/msam.3125
- Rahul AV, Santhanam M, Meena H, Ghani Z. Mechanical characterization of 3D printable concrete. Constr Build Mater. 2019;227:116710. doi: 10.1016/j.conbuildmat.2019.116710
- Bhattacherjee S, Basavaraj AS, Rahul AV, et al. Sustainable materials for 3D concrete printing. Cem Concr Compos. 2021;122:104156. doi: 10.1016/j.cemconcomp.2021.104156
- Wolfs RJM, Bos FP, Salet TAM. Hardened properties of 3D printed concrete: The influence of process parameters on interlayer adhesion. Cem Concr Res. 2019;119:132-140. doi: 10.1016/j.cemconres.2019.02.017
- Ding T, Xiao J, Zou S, Zhou X. Anisotropic behavior in bending of 3D printed concrete reinforced with fibers. Compos Struct. 2020;254:112808. doi: 10.1016/j.compstruct.2020.112808
- Wang D, Xiao J, Sun B, Zhang S, Poon CS. Mechanical properties of 3D printed mortar cured by CO2. Cem Concr Compos. 2023;139:105009. doi: 10.1016/j.cemconcomp.2023.105009
- Haselbach L. Potential for carbon dioxide absorption in concrete. J Environ Eng. 2009;135(6):465-472. doi: 10.1061/(asce)ee.1943-7870.0000004
- Sikora P, Techman M, Federowicz K, et al. Insight into the microstructural and durability characteristics of 3D printed concrete: Cast versus printed specimens. Case Stud Constr Mat. 2022;17:e01320. doi: 10.1016/j.cscm.2022.e01320
- Sun B, Dominicus R, Dong E, Li P, Ye Z, Wang W. Predicting the strength development of 3D printed concrete considering the synergistic effect of curing temperature and humidity: From perspective of modified maturity model. Constr Build Mater. 2024;427:136291. doi: 10.1016/j.conbuildmat.2024.136291
- Li L, Hao L, Li X, Xiao J, Zhang S, Poon CS. Development of CO2-integrated 3D printing concrete. Constr Build Mater. 2023;409:134233. doi: 10.1016/j.conbuildmat.2023.134233
- Kazemian M, Shafei B. Carbon sequestration and storage in concrete: A state-of-the-art review of compositions, methods, and developments. J CO2 Util. 2023;70:102443. doi: 10.1016/j.jcou.2023.102443
- Castellote M, Fernandez L, Andrade C, Alonso C. Chemical changes and phase analysis of OPC pastes carbonated at different CO2 concentrations. Mater Struct. 2009;42:515-525. doi: 10.1617/s11527-008-9399-1
- Kashef-Haghighi S, Ghoshal S. CO2 sequestration in concrete through accelerated carbonation curing in a flow-through reactor. Ind Eng Chem Res. 2010;49(3):1143-1149. doi: 10.1021/ie900703d
- Monkman S, Hwang SD, Khayat, K. Rheology modification of flowable mortar with CO2. Cem Concr Compos. 2024;151:105584. doi: 10.1016/j.cemconcomp.2024.105584
- Rahul AV, Mohan MK, De Schutter G, Van Tittelboom K. 3D printable concrete with natural and recycled coarse aggregates: Rheological, mechanical and shrinkage behaviour. Cem Concr Compos. 2022;125:104311. doi: 10.1016/j.cemconcomp.2021.104311
- An D, Zhang YX, Yang R. Incorporating coarse aggregates into 3D concrete printing from mixture design and process control to structural behaviours and practical applications: A review. Virtual Phys Prototyp. 2024;19(1):e2351154. doi: 10.1080/17452759.2024.2351154
- Wang X, Jia L, Jia Z, et al. Optimization of 3D printing concrete with coarse aggregate via proper mix design and printing process. J Build Eng. 2022;56:104745. doi: 10.1016/j.jobe.2022.104745
- Li M, Weng Y, Liu Z, Zhang D, Wong TN. Optimizing of chemical admixtures for 3D printable cementitious materials by central composite design. MSAM. 2022;1(3):16. doi: 10.18063/msam.v1i3.16
- Liu H, Liu C, Wu Y, et al. 3D printing concrete with recycled coarse aggregates: The influence of pore structure on interlayer adhesion. Cem Concr Compos. 2022;134:104742. doi: 10.1016/j.cemconcomp.2022.104742
- Liu H, Liu C, Wu Y, et al. Hardened properties of 3D printed concrete with recycled coarse aggregate. Cem Concr Res. 2022;159:106868. doi: 10.1016/j.cemconres.2022.106868
- Mai I, Brohmann L, Freund N, et al. Large particle 3D concrete printing-a green and viable solution. Materials (Basel). 2021;14(20):6125. doi: 10.3390/ma14206125
- Wang D, Xiao J, Duan Z. Strategies to accelerate CO2 sequestration of cement-based materials and their application prospects. Constr Build Mater. 2022;314:125646. doi: 10.1016/j.conbuildmat.2021.125646
- Singh R, Wang L, Ostrikov K, Huang J. Designing carbon‐based porous materials for carbon dioxide capture. Adv Mater Interf. 2024;11(4):2202290. doi: 10.1002/admi.202202290
- Al-Khowaiter AO, Jamal A, Amr IT, Bamagain R, Al-Hunaidy AS, Fadhel BA. Cementitious Print Head, 3D Printing Architecture, and Cementitious Printing Methodology. Patent No. US011236517B2; 2022.
- Lim SG, Tay YWD, Paul SC, et al. Carbon capture and sequestration with in-situ CO2 and steam integrated 3D concrete printing. Carbon Capture Sci Technol. 2024;13:100306. doi: 10.1016/j.ccst.2024.100306
- ASTM. C109/C109M-20: Standard Test Method for Compressive Strength of Hydraulic Cement Mortars (Using 2-in. or [50-mm] Cube Specimens). West Conshohocken, PA, United States: ASTM.
- ASTM. C293/C293M-16. Standard Test Method for Flexural Strength of Concrete (Using Simple Beam With Center-Point Loading). West Conshohocken, PA, United States: ASTM.
- Bhatty JI. Hydration versus strength in a portland cement developed from domestic mineral wastes-A comparative study. Thermochim Acta. 1986;106:93-103. doi: 10.1016/0040-6031(86)85120-6
- Takahashi H, Maruyama I. Quantification of CO2 in cement pastes with different degrees of carbonation. J Adv Concr Technol. 2024;22(11):706-715. doi: 10.3151/jact.22.706
- Fang X, Xuan D, Poon CS. Empirical modelling of CO2 uptake by recycled concrete aggregates under accelerated carbonation conditions. Mater Struct. 2017;50:1-13. doi: 10.1617/s11527-017-1066-y
- Bernal SA, Provis JL, Mejía de Gutiérrez R, Van Deventer JS. Accelerated carbonation testing of alkali-activated slag/ metakaolin blended concretes: Effect of exposure conditions. Mater Struct. 2015;48:653-669. doi: 10.1617/s11527-014-0289-4
- Kaliyavaradhan SK, Ling TC, Mo KH. CO2 sequestration of fresh concrete slurry waste: Optimization of CO2 uptake and feasible use as a potential cement binder. J CO2 Util. 2020;42:101330. doi: 10.1016/j.jcou.2020.101330
- Moini R, Rodriguez F, Olek J, Youngblood JP, Zavattieri PD. Mechanical properties and fracture phenomena in 3D-printed helical cementitious architected materials under compression. Mater Struct. 2024;57(7):170. doi: 10.1617/s11527-024-02437-4
- Panda B, Paul SC, Tan MJ. Anisotropic mechanical performance of 3D printed fiber reinforced sustainable construction material. Mater Lett. 2017;209:146-149. doi: 10.1016/j.matlet.2017.07.123
- Pi Y, Lu C, Li B, Zhou J. Crack propagation and failure mechanism of 3D printing engineered cementitious composites (3DP-ECC) under bending loads. Constr Build Mater. 2023;408:133809. doi: 10.1016/j.conbuildmat.2023.133809
- Wang YC, Lee MG, Wang WC, Kan YC, Kao SH, Chang HW. CO2 curing on the mechanical properties of Portland cement concrete. Buildings. 2022;12(6):817. doi: 10.3390/buildings12060817
- Shi C, Wu Y. Studies on some factors affecting CO2 curing of lightweight concrete products. Resour Conserv Recycle. 2008;52(8-9):1087-1092. doi: 10.1016/j.resconrec.2008.05.002
- Kamal NLM, Itam Z, Sivaganese Y, Beddu S. Carbon dioxide sequestration in concrete and its effects on concrete compressive strength. Mater Today Proc. 2020;31:A18-A21. doi: 10.1016/j.matpr.2020.11.185
- Lippiatt N, Ling TC. Rapid hydration mechanism of carbonic acid and cement. J Build Eng. 2020;31:101357. doi: 10.1016/j.jobe.2020.101357
- Han Y, Meng LY, Lin R, Kim S, Kim T, Wang XY. Evaluating the sustainability of microwave pre-cured high-volume slag concrete: Mechanical properties, environmental impact and cost-benefit analysis. J Build Eng. 2024;96:110663. doi: 10.1016/j.jobe.2024.110663
- Gao Y, Jiang Y, Tao Y, Shen P, Poon CS. Accelerated carbonation of recycled concrete aggregate in semi-wet environments: A promising technique for CO2 utilization. Cem Concr Res. 2024;180:107486. doi: 10.1016/j.cemconres.2024.107486
- Dixit A, Du H, Dai Pang S. Carbon capture in ultra-high performance concrete using pressurized CO2 curing. Constr Build Mater. 2021;288:123076. doi: 10.1016/j.conbuildmat.2021.123076
- Meng LY, Wang YS, Sun F, Lin R, Wang XY. An integrated strength-carbon emissions-total cost model for silica fume concrete. Case Stud Constr Mat. 2025;22:e04327. doi: 10.1016/j.cscm.2025.e04327
- O˘Guz S, Bellefontaine R, West J. Visualized: The Price of Carbon around the World in 2024. Available from: https:// www.visualcapitalist.com/sp/visualized-the-price- of-carbon-around-the-world-in-2024 [Last accessed on 2025 Jul 24].

