Achieving a balanced duplex microstructure and corrosion resistance in UNS S32707 hyper-duplex stainless steel fabricated using GMAW-based wire arc additive manufacturing
UNS S32707 Hyper-duplex stainless steels (HDSS) offer an attractive combination of high strength and corrosion resistance for demanding marine and offshore applications. A UNS S32707 HDSS wall was fabricated using gas metal arc welding (GMAW) combined with wire arc additive manufacturing (WAAM) for the subsea umbilical in marine engineering applications. The aim is to achieve a 50:50 ratio of austenite and ferrite phases and to suppress the formation of secondary phases; the balanced phase ratio provides a combination of mechanical properties and corrosion resistance. Microstructure evolution, mechanical behavior, and corrosion resistance of as-deposited UNS S32707 HDSS were comprehensively investigated. The electron backscatter diffraction analysis depicted a balanced duplex structure consisting of 52.1% ferrite, 47.4% austenite, and 0.5% sigma (σ) phase at the grain boundaries. The microstructure exhibited ferrite, intragranular austenite, Widmanstätten austenite, and grain-boundary austenite. Secondary phases, such as Cr2N, secondary austenite (γ2), and the chi (χ) phase, were not observed due to lower heat input and suitable inter-pass temperature. The tensile tests in three orientations (0°, 45°, 90°) relative to the build direction showed ultimate tensile strengths ranging from 927 MPa to 943 MPa, with elongations of 44% and an average hardness of 334 HV0.5. Fractographic analysis revealed ductile failure, exhibiting finer and more uniform dimples. The corrosion studies conducted using a potentiodynamic polarization test in a 3.5 wt.% NaCl solution showed good corrosion resistance, with a low corrosion rate of 0.07877 mm/year. These findings establish controlled GMAW-based WAAM as a promising route for producing phase-balanced UNS S32707 HDSS for demanding marine applications.

- Market Data Forecast. Duplex Stainless Steel Market Report. Accessed April 24, 2026. https://www.marketdataforecast.com/market-reports/duplex-stainless-steel-market
- Dirisu P, Supriyo G, Martina F, Xu X, Williams S. Wire plus arc additive manufactured functional steel surfaces enhanced by rolling. Int J Fatigue. 2020;130:105237. doi: 10.1016/j.ijfatigue.2019.105237
- Xiong J, Zhang G, Zhang W. Forming appearance analysis in multi-layer single-pass GMAW-based additive manufacturing. Int J Adv Manuf Technol. 2015;80(9-12):1767-1776. doi: 10.1007/s00170-015-7112-4
- Kumar MDB, Bhasith AA, Kumar GSV, et al. Investigation of Microstructure and Mechanical Characteristics of Thin-walled Hastelloy C-276 Manufactured Through Pulsed-Arc Additive Manufacturing Technique. Met Mater Int. 2025;31(2):489-507. doi: 10.1007/s12540-024-01750-5
- Ahn DG. Direct metal additive manufacturing processes and their sustainable applications for green technology: A review. Int J Precis Eng Manuf Green Technol. 2016;3(4):381-395. doi: 10.1007/s40684-016-0048-9
- Bikas H, Stavropoulos P, Chryssolouris G. Additive manufacturing methods and modelling approaches: a critical review. Int J Adv Manuf Technol. 2016;83(1-4):389-405. doi: 10.1007/s00170-015-7576-2
- Palmeira Belotti L, Van Dommelen JAW, Geers MGD, Goulas C, Ya W, Hoefnagels JPM. Microstructural characterisation of thick-walled wire arc additively manufactured stainless steel. J Mater Process Technol. 2022;299:117373. doi: 10.1016/j.jmatprotec.2021.117373
- Haghdadi N, Laleh M, Moyle M, Primig S. Additive manufacturing of steels: a review of achievements and challenges. J Mater Sci. 2021;56(1):64-107. doi: 10.1007/s10853-020-05109-0
- Raj PN, Navaneethkrishnan PK, Sekar K, Joseph MA. Comparative study of mechanical, corrosion and erosion—corrosion properties of cast hyper-duplex and super-duplex stainless steels. Int J Miner Metall Mater. 2020;27(7):954-961. doi: 10.1007/s12613-020-1984-5
- Raha B. Study on Properties of Hyper-duplex Stainless Steel 7A of ASTM A-890 (CD3MWN). Trans Indian Inst Met. 2020;73(1):127-134. doi: 10.1007/s12666-019-01811-z
- Chail G, Kangas P. Super and hyper duplex stainless steels: structures, properties and applications. Procedia Struct Integrity. 2016;2:1755-1762. doi: 10.1016/j.prostr.2016.06.221
- Xiang H, Hu Y, Cao H, Liu D, Dong X. Erosion–corrosion behavior of SAF3207 hyper-duplex stainless steel. Int J Miner Metall Mater. 2019;26(11):1415-1426. doi: 10.1007/s12613-019-1825-6
- Göransson K, Nyman ML, Holmquist M, Gomes E. Sandvik SAF 2707 HD® (UNS S32707): a hyper-duplex stainless steel for severe chloride containing environments. Rev Met Paris. 2007;104(9):411-417. doi: 10.1051/metal:2007207
- Sun L, Sun Y, Lv C, et al. Studies on the degree of sensitization of hyper-duplex stainless steel 2707 at 900℃ using a modified DL-EPR test. Corros Sci. 2021;185:109432. doi: 10.1016/j.corsci.2021.109432
- Shang F, Wang Z, Chen X, Ji Z, Ren S, Qu X. UNS S32707 hyper-duplex stainless steel processed by powder injection molding and supersolidus liquid-phase sintering in nitrogen sintering atmosphere. Vacuum. 2021;184:109910. doi: 10.1016/j.vacuum.2020.109910
- Shang F, Chen X, Wang Z, et al. The Microstructure, Mechanical Properties, and Corrosion Resistance of UNS S32707 Hyper-Duplex Stainless Steel Processed by Selective Laser Melting. Metals. 2019;9(9):1012. doi: 10.3390/met9091012
- Ding J, Colegrove P, Mehnen J, et al. Thermo-mechanical analysis of Wire and Arc Additive Layer Manufacturing process on large multi-layer parts. Comput Mater Sci. 2011;50(12):3315-3322. doi: 10.1016/j.commatsci.2011.06.023
- Xu X, Ganguly S, Ding J, et al. Improving mechanical properties of wire plus arc additively manufactured maraging steel through plastic deformation enhanced aging response. Mater Sci Eng A. 2019;747:111-118. doi: 10.1016/j.msea.2018.12.114
- Zhang X, Zhou Q, Wang K, et al. Study on microstructure and tensile properties of high nitrogen Cr-Mn steel processed by CMT wire and arc additive manufacturing. Mater Des. 2019;166:107611. doi: 10.1016/j.matdes.2019.107611
- Das A, Yadav V, AlMangour B, et al. Additive manufacturing of graphene reinforced 316L stainless steel composites with tailored microstructure and mechanical properties. Mater Chem Phys. 2023;303:127826. doi: 10.1016/j.matchemphys.2023.127826
- Pan J, Wang J, Evernden M, Evans SI, Xu F. Experimental assessment of stiffening geometries for thin-walled structural steel plates made by wire arc additive manufacturing. Results Eng. 2026;29:108966. doi: 10.1016/j.rineng.2026.108966
- Wang J, Chen W, Meng H, Cui Y, Zhang C, Han P. Influence of sigma phase on corrosion and mechanical properties of 2707 hyper-duplex stainless steel aged for short periods. J Iron Steel Res Int. 2019;26(5):452-461. doi: 10.1007/s42243-018-0175-3
- Mukherjee T, Elmer JW, Wei HL, et al. Control of grain structure, phases, and defects in additive manufacturing of high-performance metallic components. Prog Mater Sci. 2023;138:101153. doi: 10.1016/j.pmatsci.2023.101153
- Kannan AR, Shanmugam NS, Rajkumar V, Vishnukumar M. Insight into the microstructural features and corrosion properties of wire arc additive manufactured super duplex stainless steel (ER2594). Mater Lett. 2020;270:127680. doi: 10.1016/j.matlet.2020.127680
- Queguineur A, Asadi R, Ostolaza M, et al. Wire arc additive manufacturing of thin and thick walls made of duplex stainless steel. Int J Adv Manuf Technol. 2023;127(1-2):381-400. doi: 10.1007/s00170-023-11560-5
- Kumar S, Krisam S, Jacob A, et al. Microstructures and element distributions in an aged hyper duplex stainless steel and corresponding hardness variation. Mater Des. 2020;194:108951. doi: 10.1016/j.matdes.2020.108951
- De Sampaio MTG, Furtado AB, Ignácio MDC, et al. Quantification of Deleterious Phase Precipitation in a Hyper Duplex Stainless Steel Aged at 700-950 °C Using Optimized Linear Sweep Voltammetry: Effect of KOH Concentration. J Mater Eng Perform. 2025;34(13):12494-12507. doi: 10.1007/s11665-024-10049-w
- Yang R, Han S, Lei X, et al. Hot corrosion mechanism of laser metal deposited Ni-based single crystal superalloy under fuel gas atmosphere. Surf Coat Technol. 2023;474:130057. doi: 10.1016/j.surfcoat.2023.130057
- Schuster R, Keplinger A, Jacob A, et al. In-situ XRD investigation of σ phase precipitation kinetics during isothermal holding in a hyper duplex stainless steel. Mater Charact. 2023;203:113124. doi: 10.1016/j.matchar.2023.113124
- Wang H, Wang A, Li C, Yu X, Xie J, Liu C. Effect of Secondary-Phase Precipitation on Mechanical Properties and Corrosion Resistance of 00Cr27Ni7Mo5N Hyper-Duplex Stainless Steel during Solution Treatment. Materials. 2022;15(21):7533. doi: 10.3390/ma15217533
- Wang Y, Sukenaga S, Shibata H, Wang Q, Mu W. Combination of In Situ Confocal Microscopy and Calorimetry to Investigate Solidification of Super‐ and Hyper‐Duplex Stainless Steels. Steel Res Int. 2023;94(11):2200960. doi: 10.1002/srin.202200960
- Zhang Y, Wu S, Cheng F. A specially-designed super duplex stainless steel with balanced ferrite:austenite ratio fabricated via flux-cored wire arc additive manufacturing: Microstructure evolution, mechanical properties and corrosion resistance. Mater Sci Eng A. 2022;854:143809. doi: 10.1016/j.msea.2022.143809
- Eriksson M, Lervåg M, Sørensen C, et al. Additive manufacture of superduplex stainless steel using WAAM. In: Pantelakis S, Koubias S, eds. MATEC Web Conf. 2018;188:03014. doi: 10.1051/matecconf/201818803014
- Wittig B, Zinke M, Jüttner S. Influence of arc energy and filler metal composition on the microstructure in wire arc additive manufacturing of duplex stainless steels. Weld World. 2021;65(1):47-56. doi: 10.1007/s40194-020-00995-z
- Nikam PP, Arun D, Ramkumar KD, Sivashanmugam N. Microstructure characterization and tensile properties of CMT-based wire plus arc additive manufactured ER2594. Mater Charact. 2020;169:110671. doi: 10.1016/j.matchar.2020.110671
- Hengsbach F, Koppa P, Duschik K, et al. Duplex stainless steel fabricated by selective laser melting - Microstructural and mechanical properties. Mater Des. 2017;133:136-142. doi: 10.1016/j.matdes.2017.07.046
- Chen MT, Chen Y, Zuo W, et al. Experimental investigation on the tensile behavior of wire arc additively manufactured duplex stainless steel plates. Eng Struct. 2024;321:118764. doi: 10.1016/j.engstruct.2024.118764
- Kannan AR, Shanmugam NS, Ramkumar KD, Rajkumar V. Studies on Super Duplex Stainless Steel Manufactured by Wire Arc Additive Manufacturing. Trans Indian Inst Met. 2021;74(7):1673-1681. doi: 10.1007/s12666-021-02257-y
- Zhang X, Wang K, Zhou Q, et al. Microstructure and mechanical properties of TOP-TIG-wire and arc additive manufactured super duplex stainless steel (ER2594). Mater Sci Eng A. 2019;762:138097. doi: 10.1016/j.msea.2019.138097
- Chiniforoush EA, Gholizadeh T, Jandaghi MR, Moverare J, Gür CH. Impact of active to inert shielding gas transition on the corrosion behavior of wire arc additively manufactured duplex stainless steel. Mater Des. 2025;253:113907. doi: 10.1016/j.matdes.2025.113907
- Keplinger A, Martinez C, Hausbauer M, Kapp M. Early Stages of Deleterious Phases in Super and Hyper Duplex Stainless Steel and Their Effect on Toughness. Berg Huettenmaenn Monatsh. 2020;165(1):33-39. doi: 10.1007/s00501-019-00936-4
- Akbarzadeh E, Yurtışık K, Hakan Gür C, Saeid T, Tavangar R. Influence of Shielding Gas on the Microstructure and Mechanical Properties of Duplex Stainless Steel in Wire Arc Additive Manufacturing. Met Mater Int. 2024;30(7):1977-1996. doi: 10.1007/s12540-023-01623-3
- Haghdadi N, Cizek P, Hodgson PD, Tari V, Rohrer GS, Beladi H. Effect of ferrite-to-austenite phase transformation path on the interface crystallographic character distributions in a duplex stainless steel. Acta Mater. 2018;145:196-209. doi: 10.1016/j.actamat.2017.11.057
- He XY, Xu ZP, Rohrer GS, Kong C, Primig S, Haghdadi N. Three-dimensional analysis of the delta-ferrite to austenite phase transformation in an additively manufactured duplex stainless steel. Mater Charact. 2025;221:114745. doi: 10.1016/j.matchar.2025.114745
- Biradar NS, Raman R. Grain Refinement in Al-Mg-Si Alloy TIG Welds Using Transverse Mechanical Arc Oscillation. J Mater Eng Perform. 2012;21(11):2495-2502. doi: 10.1007/s11665-012-0207-2
- Eghlimi A, Shamanian M, Eskandarian M, Zabolian A, Szpunar JA. Characterization of microstructure and texture across dissimilar super duplex/austenitic stainless steel weldment joint by austenitic filler metal. Mater Charact. 2015;106:208-217. doi: 10.1016/j.matchar.2015.05.036
- Abe M, Hiura A, Ishida K, Nishizawa T. Grain Growth in Duplex Stainless Steels. Tetsu-to-Hagane. 1984;70(15):2025-2032. doi: 10.2355/tetsutohagane1955.70.15_2025
- Chiniforoush EA, Gholizadeh T, Jandaghi MR, Moverare J, Gür CH. Investigation of travel speed effects on microstructure and corrosion behavior of duplex stainless steel in wire-based DED additive manufacturing. J Mater Res Technol. 2025;37:1486-1504. doi: 10.1016/j.jmrt.2025.06.143
- Krupp U, Söker M, Giertler A, et al. The potential of spinodal ferrite decomposition for increasing the very high cycle fatigue strength of duplex stainless steel. Int J Fatigue. 2016;93:363-371. doi: 10.1016/j.ijfatigue.2016.05.012
- Van Ede MC, Angst U. Tafel slopes and exchange current densities of oxygen reduction and hydrogen evolution on steel. Corros Eng Sci Technol. 2024;59(1):39-55. doi: 10.1177/1478422X241227829
- Murmu M, Saha SKr, Murmu NC, Banerjee P. Amine cured double Schiff base epoxy as efficient anticorrosive coating materials for protection of mild steel in 3.5% NaCl medium. J Mol Liq. 2019;278:521-535. doi: 10.1016/j.molliq.2019.01.066
- Cai S, Lu K, Li X, Wen L, Huang F, Jin Y. Quantitative micro-electrochemical study of duplex stainless steel 2205 in 3.5wt% NaCl solution. Int J Miner Metall Mater. 2022;29(11):2053-2063. doi: 10.1007/s12613-021-2291-5
- Li H, Zhou E, Zhang D, et al. Microbiologically Influenced Corrosion of 2707 Hyper-Duplex Stainless Steel by Marine Pseudomonas aeruginosa Biofilm. Sci Rep. 2016;6(1):20190. doi: 10.1038/srep20190
