Solidification of river sediment by mayenite and biochar composite stabilizers: Strength development, microstructural evolution, and leaching behavior
The resource utilization of urban river sediments is often hindered by their high-water content, poor mechanical properties, and potential environmental risks. In this study, a composite stabilization system based on mayenite (CA) and coconut-shell biochar (BC) was developed to simultaneously improve the engineering performance and environmental safety of contaminated sediments. The effects of initial water content, CA dosage, CA particle size, BC dosage, and BC particle size were systematically investigated using unconfined compressive strength (UCS) tests. The optimal conditions were 70% initial water content, 40% CA (250 mesh), and 20% BC (200 mesh), achieving a maximum UCS of 2.31 ± 0.11 MPa. Microstructural analyses revealed distinct functional roles of the two stabilizers. CA primarily provided mechanical stabilization by forming cementitious hydration products that bound sediment particles into a dense, continuous matrix, whereas BC mainly enhanced environmental stabilization through pore refinement and adsorption-assisted contaminant retention. As a result, the CA–BC composite significantly reduced the leaching of heavy metals, chemical oxygen demand, total nitrogen, and total phosphorus compared to CA stabilization alone. This study demonstrates that CA and BC play complementary roles in sediment stabilization, with CA dominating mechanical reinforcement and BC enhancing environmental stability, providing an effective strategy for the sustainable reuse of dredged sediments in geotechnical engineering.
- Beljin J, Slijepčević N, Duduković N, Tomašević Pilipović D. Sediment pollution: unraveling its impact on water quality, resource management and navigating towards sustainable development goals. Int J Environ Sci Technol. 2026;23:525. doi: 10.1007/s13762-026-07329-4
- Mahfoud E, Ndiaye K, Maherzi W, Aggoun S, Benzerzour M, Abriak N-E. Mechanical properties and shrinkage performance of one-part-geopolymer based on fly ash and micronized dredged sediments. Dev Built Environ. 2023;16:100253. doi: 10.1016/j.dibe.2023.100253
- Zhang Z, Cui Y, Ma J, et al. Analysis and prospect of treatment measures for black-odorous water sediment in China. E3S Web Conf. 2020;194:04005. doi: 10.1051/e3sconf/202019404005
- Chen Z, You N, Chen C, Zhang Y. Properties of dredged sludge solidified with alkali-activated slag-based materials and blended with copper slag as fine aggregates of mortars. Constr Build Mater. 2021;312:125459. doi: 10.1016/j.conbuildmat.2021.125459
- Wang S, He X, Cai G, et al. Strength characteristic and micro-mechanism of organic dredged sludge solidified by cement incorporating sodium persulfate. Dev Built Environ. 2024;17:100323. doi: 10.1016/j.dibe.2024.100323
- Zheng W, Yu J, Cai Y, Weng Z. Evaluating the engineering performance and mechanisms of sodium lignosulfonate-modified mineral cementitious materials in fluidized solidified coastal sediment. Constr Build Mater. 2026;514:145563. doi: 10.1016/j.conbuildmat.2026.145563
- Wang H, Ding Y, Dong L, Wang D, Sun D, Yan F. Solidified high moisture and high organic content sediment as liquefied backfill material for urban underground space. Acta Geotech. 2026. doi: 10.1007/s11440-026-02960-4
- Feng J, Yu Y, Huang S, Zhu N, Mojiri A, Ge D. Tannic acid as a green chemical for the removal of various heavy metals: A critical review of recent developments. J Environ Manage. 2025;375:124390. doi: 10.1016/j.jenvman.2025.124390
- Wang J, Wang H, Ding J, Ni J, Mou C, Wan X. Investigation on performance improvement of dredged sediment with high water content stabilized with alkali-activated materials. J Soils Sediments. 2024;24(3):1464-1473. doi: 10.1007/s11368-023-03680-y
- Cino CM, Petrella A, Todaro F, Notarnicola M. Recycling of marine sediments in cement-based materials by stabilization/solidification treatment: Effect on the mechanical and microstructural properties. Recycling. 2025;10(5):169. doi: 10.3390/recycling10050169
- Mastoi AK, Alidekyi SN, Ali M, Channa IA, Dahri AA, Khan U. Effect of flocculant and Tartaric acid on solidification behavior of GGBS-MgO solidified dredged slurry treated with chemical-physical combined method. Int J Environ Sci Technol. 2025;22(14):14173-14184. doi: 10.1007/s13762-025-06550-x
- Zhao C, Sun Y, Wu Z, Lv J, Peng D, Meng C. Calcium silicate hydrate-mediated in-situ phosphorus immobilization facilitates subsequent eutrophic sediment dewatering through structure reorganization. Chem Eng J. 2026;535:175573. doi: 10.1016/j.cej.2026.175573
- Yu Y, Feng J, Zhu N, Ge D. Ferric tannate-enhanced electrochemical conditioning process for improving sludge dewaterability. Water. 2025;17(16):2424. doi: 10.3390/w17162424
- Wu R, Liu Y, Zhang S, et al. Characterization of nitrogen and phosphorus at the ice-water-sediment interface and the effect of their migration on overlying water quality in Daihai Lake (China) during the freezing period. Sci Total Environ. 2023;893:164863. doi: 10.1016/j.scitotenv.2023.164863
- Xu Q, Wu B, Chai X. In situ remediation technology for heavy metal contaminated sediment: A review. Int J Environ Res Public Health. 2022;19(24):16767. doi: 10.3390/ijerph192416767
- Wang H, Zentar R, Wang D, Ouendi F. New applications of ordinary portland and calcium sulfoaluminate composite binder for recycling dredged marine sediments as road materials. Int J Geomech. 2022;22(6):04022068. doi: 10.1061/(ASCE)GM.1943-5622.0002373
- Arairo W, Hamd W, Al Sahmarany B, Ghannoum M, Affan H, Barraj F. Influence of lime stabilization and natural fiber reinforcement on the performance of sediment-based blocks for sustainable construction. Discov Sustain. 2026;7:1299. doi: 10.1007/s43621-026-03724-6
- Zhou S, Zhang H, Lv J, et al. Valorization of dredged sediment through Al3+-mediated C–A–S–H gel networks: Bridging mechanisms for enhanced structural bonding in non-autoclaved brick production. J Environ Chem Eng. 2025;13(5):118681. doi: 10.1016/j.jece.2025.118681
- Deng Y, Yue Z, Wang Z, Huang Q, Yang X. Optimization and mechanism of the novel eco-friendly additives for solidification and stabilization of dredged sediment. Environ Sci Pollut Res. 2024;31(17):25964-25977. doi: 10.1007/s11356-024-32865-2
- Cai G-H, Zhou Y-F, Poon CS, Li J-S. Engineering performance and microstructure characteristics of natural marine sediment stabilized with quicklime-activated GGBS under different lime proportions. Mar Georesour Geotechnol. 2023;41(8):858-872. doi: 10.1080/1064119X.2022.2105765
- Lourenço RR, Angélica RS, Rodrigues JDA. Preparation of refractory calcium aluminate cement using the sonochemical process. Mater Res. 2013;16(4):731-739. doi: 10.1590/S1516-14392013005000041
- Luo J, Cai Y, Yu J, Huang J, Yan J, Zhu Y. A laboratory evaluation of enhanced stabilization of dredged heavy metal-contaminated coastal sediments using a green biochar-metakaolin-sodium silicate composite: Performance, mechanisms, and applications. J Clean Prod. 2026;566:148542. doi: 10.1016/j.jclepro.2026.148542
- Luo J, Cai Y, Yu J, Huang J, Yan J. Immobilization and stabilization of heavy metals in coastal sediments using polycrystalline silicon-aluminum biochar-based material GBMSS: Mechanisms and performance. Chem Eng J. 2025;519:165510. doi: 10.1016/j.cej.2025.165510
- Gu X, Guo P, Li Z, et al. A multifunctional coconut shell biochar modified by titanium dioxide for heavy metal removal in water/soil and tetracycline degradation. J Clean Prod. 2024;482:144192. doi: 10.1016/j.jclepro.2024.144192
- Ajien A, Idris J, Md Sofwan N, Husen R, Seli H. Coconut shell and husk biochar: A review of production and activation technology, economic, financial aspect and application. Waste Manag Res. 2023;41(1):37-51. doi: 10.1177/0734242X221127167
- Ministry of Ecology and Environment of the People’s Republic of China. Solid waste-extraction procedure for leaching toxicity-sulphuric acid and nitric acid method (HJ/T 299–2007). Beijing, China: China Environmental Science Press; 2007. Accessed September 2, 2026. https://www.mee.gov.cn/ywgz/fgbz/bz/bzwb/jcffbz/200704/t20070418_102859.shtml
- Ministry of Ecology and Environment of the People’s Republic of China. Water quality–Digestion of total metals–Nitric acid digestion method (HJ 677–2013). Beijing, China: China Environmental Science Press; 2013. Accessed September 2, 2026. https://www.mee.gov.cn/ywgz/fgbz/bz/bzwb/jcffbz/201312/t20131203_264301.htm
- Ministry of Ecology and Environment of the People’s Republic of China. Water quality–Determination of the chemical oxygen demand–Fast digestion-spectrophotometric method (HJ/T 399–2007). Beijing, China: China Environmental Science Press; 2007. Accessed September 2, 2026. https://www.mee.gov.cn/ywgz/fgbz/bz/bzwb/jcffbz/200712/t20071213_114284.htm
- Ministry of Environmental Protection of the People’s Republic of China. Water quality–Determination of total nitrogen–Alkaline potassium persulfate digestion UV spectrophotometric method (HJ 636–2012). Beijing, China: China Environmental Science Press; 2012. Accessed September 2, 2026. https://www.mee.gov.cn/ywgz/fgbz/bz/bzwb/jcffbz/201203/t20120307_224383.shtml
- Ministry of Ecology and Environment of the People’s Republic of China. Water quality–Determination of total phosphorus–Ammonium molybdate spectrophotometric method (GB 11893–89). Beijing, China: China Environmental Science Press; 1989. Accessed September 2, 2026. https://openstd.samr.gov.cn/bzgk/std/newGbInfo?
hcno=E3834D3D19D975F69C69CB359BCB762E - Gupta S, Kua HW. Carbonaceous micro-filler for cement: Effect of particle size and dosage of biochar on fresh and hardened properties of cement mortar. Sci Total Environ. 2019;662:952-962. doi: 10.1016/j.scitotenv.2019.01.269
- Zhu Y, Chen S, Zhong F, et al. Solidified dredged sediment as ecological restoration substrate: mechanical strength, water stability, and vegetation performance. J Soils Sediments. 2026;26(1):12. doi: 10.1007/s11368-025-04223-3
- Ma Q, Wang K, Li Q, Zhang Y. Alkali-activated dredged-sediment-based fluidized solidified soil: Early-age engineering performance and microstructural mechanisms. Materials. 2025;18(14):3408. doi: 10.3390/ma18143408
- Wang H, Zhang J, Sun D, Li Y, Shi Y. Sustainable solidification/stabilization of high-moisture dredged sediment using solid waste-based cementitious materials blended with OPC: Strength, environmental impact, and micro-mechanism. J Environ Chem Eng. 2026;14(3):122347. doi: 10.1016/j.jece.2026.122347
- Shi Y, Zhang S, Gao P, Xie W, Wang C, Chen B. Reaction mechanism regulation in high-phosphogypsum supersulfated cement: Nano-metakaolin–induced formation of a compact AFt/C-(A)-S-H network and immobilization of phosphorus and fluorine. Constr Build Mater. 2026;512:145347. doi: 10.1016/j.conbuildmat.2026.145347
- Zhou H, Zhang H, Zhang Y, et al. Solidification/stabilization of composite heavy metal‐contaminated soil by red mud‐slag‐based geopolymer. J Appl Polym Sci. 2026;143(35):e71049. doi: 10.1002/app.71049
- Pituello C, Francioso O, Simonetti G, et al. Characterization of chemical-physical, structural and morphological properties of biochars from biowastes produced at different temperatures. J Soils Sediments. 2015;15(4):792-804. doi: 10.1007/s11368-014-0964-7
- Zhang J, Yu Y, Li W, et al. A novel sludge dewatering conditioner of chitin derivatives from waste black soldier fly puparia: Efficacy, key factors, and mechanisms. Process Saf Environ Prot. 2025;202:107789. doi: 10.1016/j.psep.2025.107789
- Ruttanapun C, Srepusharawoot P, Maensiri S. Effect of Fe3+-doped Ca12Al14O33 cement on optical and thermal properties. Chin J Phys. 2018;56(1):252-260. doi: 10.1016/j.cjph.2017.12.022
- Wang L, Tsang D, Poon C. Green remediation and recycling of contaminated sediment by waste-incorporated stabilization/solidification. Chemosphere. 2015;122:257-264. doi: 10.1016/j.chemosphere.2014.11.071
- Sun Z, Chen W, Zhao R, Jin Y, Yin J. Solidification/stabilization treatment of Hong Kong marine deposits slurry at high water content by ISSA and GGBS. Constr Build Mater. 2023;372:130817. doi: 10.1016/j.conbuildmat.2023.130817
- State Environmental Protection Administration of China, General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China. Identification standards for hazardous wastes–Identification for extraction toxicity (GB 5085.3–2007). Beijing, China: China Environmental Science Press; 2007. Accessed September 2, 2026. https://www.mee.gov.cn/ywgz/fgbz/bz/bzwb/gthw/wxfwjbffbz/200705/t20070522_103957.shtml
