AccScience Publishing / AJWEP / Volume 21 / Issue 1 / DOI: 10.3233/AJW240003
RESEARCH ARTICLE

Magnetic Nanocomposites for Removal of Arsenic from Water 

Md. Ahmaruzzaman 1
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1 Department of Chemistry, National Institute of Technology, Silchar – 788010, Assam, India
AJWEP 2024, 21(1), 11–16; https://doi.org/10.3233/AJW240003
Submitted: 31 May 2022 | Revised: 29 August 2023 | Accepted: 29 August 2023 | Published: 6 February 2024
© 2024 by the Author(s). This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution -Noncommercial 4.0 International License (CC-by the license) ( https://creativecommons.org/licenses/by-nc/4.0/ )
Abstract

Arsenic significantly impacts human health and the environment and its removal from wastewater is still difficult. Magnetic nanoparticles have come to light as a viable arsenic remediation technique, providing a fresh and long-lasting water purification method. This study investigates the use of magnetic nanoparticles to remove arsenic by concentrating on their adsorption mechanism, kinetics, potential for adsorption, recovery, and promising use of this method in the future. Due to the extensive surface area and variable surface chemistry of magnetic nanoparticles, they can effectively adsorb arsenic from water sources. Because their magnetic properties simplify separation and regeneration, they may be used again with little to no efficiency loss. As a result, they reduce trash output by providing an ecologically acceptable alternative to traditional adsorbents. The present study also examines the kinetics and adsorption process of magnetic nanoparticles, emphasising their improved selectivity and capacity for adsorption. Due to these characteristics, the authors were able to successfully remove arsenic from wastewater, resulting in better water quality and decreased health hazards after exposure to arsenic. Additionally, the potential applications of magnetic nanoparticles in removing arsenic have been highlighted. It is envisaged that advances in material science and nanotechnology will create unique magnetic nanoparticles with even better performance. Combining hybrid materials and surface alterations can increase their effectiveness in wastewater treatment settings.

Keywords
Magnetic
nano-adsorbents
arsenic
removal
wastewater
water
References

Ahmaruzzaman, M. and D.K. Sharma (2005). Adsorption of  phenols from wastewater. Journal of Colloid and Interface Science, 287(1): 14-24. 

Ahmaruzzaman, M. and S.L. Gayatri (2010a). Batch adsorption of 4-nitrophenol by acid activated jute stick char: Equilibrium, kinetic and thermodynamic studies. Chemical Engineering Journal, 158(2): 173-180.

Ahmaruzzaman, M. and S.L. Gayatri (2010b). Activated tea waste as a potential low-cost adsorbent for the removal of p-nitrophenol from wastewater. Journal of Chemical & Engineering Data, 55(11): 4614-4623.

Ahmaruzzaman, M. (2011). Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals. Advances in Colloid and Interface Science, 166 (1-2): 36-59.

Ahmaruzzaman, M., Mohanta, D. and A. Nath (2019). Environmentally benign fabrication of SnO2-CNT nanohybrids and their multifunctional efficiency as an adsorbent, catalyst and antimicrobial agent for water
decontamination. Scientific Reports, 9(1): 1-19.

Ahmed, M.J.K., Ahmaruzzaman, M. and R.A. Reza (2014). Lignocellulosic-derived modified agricultural waste: Development, characterization and implementation in sequestering pyridine from aqueous solutions. Journal of Colloid and Interface Science, 428: 222-234.

Ahmed, M.J.K. and M. Ahmaruzzaman (2015) A facile synthesis of Fe3O4-charcoal composite for the sorption of a hazardous dye from aquatic environment. Journal of Environmental Management, 163: 163-173.

Ahmed, M.J.K. and M. Ahmaruzzaman (2016) A review on potential usage of industrial waste materials for binding heavy metal ions from aqueous solutions. Journal of Water Process Engineering, 10: 39-47.

Babu, C.M., Vinodh, R., Sundaravel, B., Abidov, A., Peng, M.M., Cha, W.S. and H.T. Jang (2016). Characterization of reduced graphene oxide supported mesoporous Fe2O3/TiO2 nanoparticles and adsorption of As(III) and As(V) from potable water. Journal of Taiwan Institute of Chemical Engineering, 62: 199-208. 

Brammer, H. and P. Ravenscroft (2009). Arsenic in groundwater: A threat to sustainable agriculture in South and South-East Asia. Environmental International, 35(3): 647-654.

Deliyanni, E.A., Bakoyannnnakis, D.N., Zouboulis, A.I. and K.A. Matis (2003). Sorption of As(V) ions by akaganeitetype nanocrystals. Chemosphere, 50: 155-163.

Deliyanni, E.A., Nalbandian, L.K. and A. Matis (2006). Adsorptive removal of arsenites by a nanocrystalline hybrid surfactant–akaganeite sorbent. Journal of Colloid and Interface Science, 302(2): 458-466.

Deng, M., Wu, X., Zhu, A., Zhang, Q. and Q. Liu (2019). Well-dispersed TiO2 nanoparticles anchored on Fe3O4 magnetic nanosheets for efficient arsenic removal. Journal of Environmental Management, 237: 63-74.

Farideh, J.B., Najafpoor, A.A., Davoudi, M., et al. (2018). Adsorptive removal of arsenic from aqueous solutions using magnetite nanoparticles and silica-coated magnetite nanoparticles. Environ. Prog. Sustainable Energy, 37: 951-960.

Gayatri, S.L. and M. Ahmaruzzaman (2010). Adsorption technique for the removal of phenolic compounds from wastewater using low-cost natural adsorbents. Journal of Science and Technology, 5(2): 156-166. 

Hao, L., Liu, M., Wang, N. and G. Li (2018). A critical review on arsenic removal from water using iron-based adsorbents. RSC Adv., 8: 39545-39560.

Hu, Q., Liu, Y., Gu, X. and Y. Zhao (2017). Adsorption behavior and mechanism of different arsenic species on mesoporous MnFe2O4 magnetic nanoparticles. Chemosphere, 181: 328-336.

Karakaş, Z.K., Boncukcuoğlu, R. and I.H. Karakaş (2017). Adsorptive properties of As (III) from aqueous solution using magnetic nickel ferrite (NiFe2O4) nanoparticles: Isotherm and kinetic studies. Separation Science and Technology, 52(1): 21-34.

Kumar, A.S.K. and S.J. Jiang (2017). Synthesis of magnetically separable and recyclable magnetic nanoparticles decorated with β-cyclodextrin functionalized graphene oxide an excellent adsorption of As(V)/(III). Journal of Molecular Liquids, 237: 387-401.

Liu, Z., Zhang, F.S. and R. Sasai (2010). Arsenate removal from water using Fe3O4-loaded activated carbon prepared from waste biomass. Chemical Engineering Journal, 160(1): 57-62.

Magalhaes, M.C.F. (2002) Arsenic: An environmental problem limited by solubility. Pure and Applied Chemistry, 74(10): 1843-1850.

Mishra, A.K. and S. Ramaprabhu (2010). Magnetite decorated multiwalled carbon nanotube based supercapacitor for arsenic removal and desalination of seawater. Journal of Physical Chemistry C, 114: 2583-2590.

Mishra, S.R., Gadore, V. and M. Ahmaruzzaman (2023). Novel 3D sphere-like β-In2S3/Biochar nanoflowers for remediation of dyes in single and binary systems and interpretation using statistical physical
modeling. Environmental Nanotechnology, Monitoring & Management, 20: 100807.

Mishra, S.R., Gadore, V. and M. Ahmaruzzaman (2023b). Development of high-performance bi-functional novel CdSnS2 atom clusters for adsorption of rose Bengal and AOP-assisted degradation of methylene blue. Environmental Science: Water Research & Technology, 9(2): 586-602.

Mohanta, D. and M. Ahmaruzzaman (2018). Bio-inspired adsorption of arsenite and fluoride from aqueous solutions using activated carbon@SnO2 nano-composites: Isotherms, kinetics, thermodynamics, cost estimation and regeneration studies. Journal of Environmental Chemical Engineering, 6(1): 356-366.

Park, W.K., Yoon, Y.J., Kim, S., Yoo, S., Do, Y., Kang, J.W., Yoon, D.H. and W.S. Yang (2016). Feasible water flow filter with facilely functionalized Fe3O4-non-oxidative graphene/ CNT composites for arsenic removal. Journal of Environmental Chemical Engineering, 4: 3246-3252.

Paul, B., Parashar, V. and A. Mishra (2015). Graphene in the Fe3O4 nano-composite switching the negative influence of humic acid coating into an enhancing effect in the removal of arsenic from water. Environmental Science: Water Research and Technology, 1: 77-83.

Ramos Guivar, J.A., Bustamante D. A., Gonzalez, J.C., Sanches, E.A., Morales, M.A., Raez, J.M., López-Muñoz, M.J. and A. Arencibia (2018) Adsorption of arsenite and arsenate on binary and ternary magnetic nano-composites with high iron oxide content. Applied Surface Science, 454: 87-100.

Rashid, M., Sterbinsky, G.E., Pinilla, M.Á.G., Cai, Y. and K.E. O’Shea (2018). Kinetic and mechanistic evaluation of inorganic arsenic species adsorption onto humic acid grafted magnetite nanoparticles. Journal of Physical Chemistry C, 122(25): 13540-13547.

Redlich, O. and D.I. Peterson (1959). A useful adsorption isotherm. Journal of Physical Chemistry, 63: 1024-1026.

Sahu, U.K., Sahu, S., Mahapatra, S.S. and R.K. Patel (2017). Cigarette soot activated carbon modified with  Fe3O4 nanoparticles as an effective adsorbent for As(III) and As(V): material preparation, characterization and adsorption mechanism study. Journal of Molecular Liquids, 243: 395-405.

Sankararamakrishnan, N., Gupta, A. and S.R. Vidyarthi (2014). Enhanced arsenic removal at neutral pH using functionalized multiwalled carbon nanotubes. Journal of Environmental Chemical Engineering, 2: 802-810.

Sikder, M.T., Tanaka, S., Saito, T. and M. Kurasaki (2014). Application of zero-valent iron impregnated chitosancaboxymethyl β-cyclodextrin composite beads as arsenic sorbent. Journal of Environmental Chemical Engineering, 2: 370-376.

Sips, R. (1948). The structure of a catalyst surface. Journal of Physical Chemistry, 16: 490-495.

Tamaddoni Moghaddam, S., Naimi-Jamal, M.R., Rohlwing, A., Hussein, F.B. and N. Abu-Zahra (2019). High removal capacity of arsenic from drinking water using modified magnetic polyurethane foam nano-composites. Journal of Polymers and the Environment, 27(7): 1497- 1504.

Vijayaraghavan, K., Padmesh, T.V.N., Palanivelu, K. and M. Velan (2006). Biosorption of nickel(II) ions onto Sargassum wightii: Application of two-parameter and three-parameter isotherm models. Journal of Hazardous Materials, 133(1-3): 304-308.

Yang, J.C. and X.B. Yin (2017). CoFe2O4@MIL-100(Fe) hybrid magnetic nanoparticles exhibit fast and selective adsorption of arsenic with high adsorption capacity. Scientific Reports, 7: 40955.

Yu, X., Tong, S., Ge, M., Zuo, J., Cao, C., and W. Song (2013). One-step synthesis of magnetic composites of cellulose@iron oxide nanoparticles for arsenic removal. Journal of Materials Chemistry A, 1: 959-965.

Zeng, H. , Zhai, L. , Zhang, J. and D. L i (2021). As(V) adsorption by a novel coreshell magnetic nanoparticles prepared with Iron-containing water treatment residuals. Science of the Total Environment, 753: 142002.

Zhu, H., Jia, Y., Wu, X. and H. Wang (2009). Removal of arsenic from water by supported nano zero-valent iron on activated carbon. Journal of Hazardous Materials, 172: 1591-1596.

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Asian Journal of Water, Environment and Pollution, Electronic ISSN: 1875-8568 Print ISSN: 0972-9860, Published by AccScience Publishing