AccScience Publishing / AJWEP / Volume 20 / Issue 5 / DOI: 10.3233/AJW230062
RESEARCH ARTICLE

Effect of Ag Doping on ZnO/V2O5 Nanoparticles as a Photo Catalyst for the Removal of Maxillion Blue (GRL) Dye

Ahmed Mesehour Ali Refaas1,2 Enas M. AL-Robayi3 Ayad F. Alkaim4 *
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1 Department of Physics, College of Science, University of Babylon, Iraq
2 Ministry of Education, Al-Muthana, Iraq
3 Department of Physics, College of Science for Women, University of Babylon, Babylon, Iraq
4 Department of Chemistry, College of Science for Women, University of Babylon, Babylon, Iraq
AJWEP 2023, 20(5), 25–31; https://doi.org/10.3233/AJW230062
Submitted: 27 June 2023 | Revised: 4 August 2023 | Accepted: 4 August 2023 | Published: 9 October 2023
© 2023 by the Author(s). This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution -Noncommercial 4.0 International License (CC-by the license) ( https://creativecommons.org/licenses/by-nc/4.0/ )
Abstract

In this research, the photo catalytic degradation of textile dyes as a model Maxillion Blue (GRL) dye by using Ag/ZnO/V2O5 nanocomposites synthesised via hydrothermal method. The physical properties of the as-synthesised nanocomposites were examined using characterisation techniques such as scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), TEM, and UV-vis spectroscopy. the production of pure ZnO, V2O5 nanoparticles and the discovery, by XRD analysis, of diffraction peaks related to the hexagonal phase of ZnO, V2O5, UV-vis spectroscopic calculations of the nanocomposite’s energy bandgap (2.63 eV) indicated that it might function as a photo catalyst when exposed to UV-visible light. XRD also supported the fabrication of the ZnO/V2O5 nanocomposite. FE-SEM images showed that the object was spherical and somewhat hexagonal in form. EDX analysis reveals the presence of Zn, V, and O in the nanocomposite; its photocatalytic activity was evaluated through the degradation of GRL dye under exposure to solar light. The results showed that the optimum mass nanocomposite for efficient photo degradation was 0.4 g/L, with a degradation efficiency of 91.6%.

Keywords
Textile dyes
zinc oxide
maxillion blue (GRL)
hydrothermal
photo catalyst
nanoparticles
References

Abass, K.H., Shinen, M.H. and A.F. Alkaim (2018). Preparation of TiO2 nanolayers via sol-gel method and study the optoelectronic properties as solar cell applications. Journal of Engineering and Applied Sciences, 13(22): 9631-9637.

Abd, I.K., Abdulrazzak, F.H. and Z.T. Khodair (2020). Synthesis of MWCNTs from methanol/butanol mixture by catalytic chemical vapor deposition and application to synthesized dye sensitizer solar cell. Paper presented at the 2nd International Conference on Materials Engineering and Science, University of Technology Baghdad-Iraq.

Abdulrazzak, F.H. (2016). Enhance photocatalytic activity of TiO2 by carbon nanotubes. International Journal of ChemTech Research, 9(3): 431-443.

Abdulrazzak, F.H., Abbas, A.M. and F.H. Hussein (2019). Synthesis of multi-walled carbon nanotubes from Iraqi natural gas/Co mixture by catalytic flame fragments deposition method. Asian Journal of Chemistry, 31(1): 247-250.

Abdulrazzak, F.H. and F.H. Hussein (2018). Photocatalytic hydrogen production on nanocomposite of carbon nanotubes and TiO2. Journal of Physics: Conference Series, 1032: 012056.

Abdulrazzak, F.H., Jawad, M.A., Alkadir, O.K.A. and A.F. Alkaim (2021). Antimicrobial activity of Ag:ZnO/ MWCNT against Cinetobacter baumannii. Journal of Nanostructures, 11(2): 317-322.

Abdulrazzak, F.H., Jimaa, R.B., Radhi, I.M. and T.A. Himdan (2021). XRD and microscopic images for synthesis graphite nanoparticles by oxidation method. NeuroQuantology, 19(2): 45-49.

Al-Gubury, H.Y., Fairooz, N.Y., Aljeboree, A.M., Alqaraguly, M.B. and A.F. Alkaim (2015). Photcatalytic degradation n-undecane using coupled ZnO-Co2O3. International Journal of Chemical Sciences, 13(2): 863-874.

Algubili, A.M., Alrobayi, E.M. and A.F. Alkaim (2015). Photocatalytic degradation of remazol brilliant blue dye by ZnO/UV process. International Journal of Chemical Sciences, 13(2): 911-921.

Ali, R., Radhi, I.M., Ismail, A.A. and F.H. Abdulrazzak (2019). Modified ZnO for efficient photo-catalysis by Silver/Graphite oxide nanoparticles. Journal of Global Pharma Technology, 11(7): 143-150.

Aljeboree, A.M., Alshirifi, A.N. and A.F. Alkaim (2019). Activated carbon (as a waste plant sources)-clay micro/ nanocomposite as effective adsorbent: Process optimization for ultrasound-assisted adsorption removal of amoxicillin drug. Plant Archives, 19: 915-919.

Alkaim, A.F. and A.M. Ajobree (2020). White marble as an alternative surface for removal of toxic dyes (methylene blue) from aqueous solutions. International Journal of Advanced Science and Technology, 29(5): 5470-5479.

Bader, A.T., Zaied, A.M. Aljeboree, A.M. and A.F. Alkaim (2019). Removal of methyl violet (MV) from aqueous solutions by adsorption using activated carbon from pine husks (plant waste sources). Plant Archives, 19: 898-901.

Hashim, F.S., Alkaim, A.F., Mahdi, S.M. and A.H. Omran Alkhayatt (2019). Photocatalytic degradation of GRL dye from aqueous solutions in the presence of ZnO/ Fe2O3 nanocomposites. Composites Communications, 16: 111-116.

Hashim, F.S., Alkaim, A.F., Salim, S.J. and A.H.O. Alkhayatt (2019). Effect of (Ag, Pd) doping on structural, and optical properties of ZnO nanoparticales: As a model of photocatalytic activity for water pollution treatment. Chemical Physics Letters, 737: 136828.

Jamil, D. M., Al-Okbi, A.K., Hanon, M.M., Rida, K.S., Alkaim, A.F., Al-Amiery, A.A., Kadhim, A. and A.H. Kadhum (2018). Carbethoxythiazole corrosion inhibitor: As an experimentally model and DFT theory. Journal of Engineering and Applied Sciences, 13(11): 3952-3959.

Karam, F.F., Kadhim, M.I. and A.F. Alkaim (2015). Optimal conditions for synthesis of 1, 4-naphthaquinone by photocatalytic oxidation of naphthalene in closed system reactor. International Journal of Chemical Sciences, 13(2): 650-660.

Khedaer, Z., Ahmed, D.S. and S.M.H. Al-Jawad (2021). Investigation of morphological, optical, and antibacterial properties of hybrid ZnO-MWCNT prepared by sol-gel. Journal of Applied Sciences and Nanotechnology, 1(2): 66-77.

Mashkour, M.S., Al-Kaim, A.F., Ahmed, L.M. and F.H. Hussein (2011). Zinc oxide assisted photocatalytic decolorization of reactive red 2 dye. International Journal of Chemical Sciences, 9(3): 969-979.

Mosaa, Z.A., Bader, A.T., Aljeboree, A.M. and A.F. Alkaim (2019). Adsorption and removal of textile dye (methylene blue mb) from aqueous solution by activated carbon as a model (apricot stone source waste) of plant role in environmental enhancement. Plant Archives, 19: 910-914.

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Asian Journal of Water, Environment and Pollution, Electronic ISSN: 1875-8568 Print ISSN: 0972-9860, Published by AccScience Publishing