AccScience Publishing / AJWEP / Volume 2 / Issue 1 / DOI: 10.3233/AJW-2005-2_1_09
RESEARCH ARTICLE

Copper based Fenton’s System for the Decolourization of Synthetic Dyes and Dye Industry Effluents

Vishal Shah1* Manish Bhatt1 Pavel Stopka2 František Nerud1
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1 Laboratory of Biochemistry of the Wood-rotting Fungi, Institute of Microbiology ASCR, Videnska 1083, 142 20, Prague 4, Czech Republic
2 Institute of Inorganic Chemistry, ASCR, 250 68 ÍRez, Czech Republic
AJWEP 2005, 2(1), 61–64; https://doi.org/10.3233/AJW-2005-2_1_09
Submitted: 10 August 2004 | Accepted: 11 November 2004 | Published: 1 January 2005
© 2005 by the Author(s). This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution -Noncommercial 4.0 International License (CC-by the license) ( https://creativecommons.org/licenses/by-nc/4.0/ )
Abstract

The effectiveness of Cu(I) and Cu(II) Fenton’s system to decolourize a wide range of structurally different synthetic dyes was investigated. The Cu(I)/peroxide system can effectively decolourize aridine orange, basic blue 17, bromo cresol purple, reactive blue 5, evans blue, Chicago sky blue, methyl orange, methyl red, neutral red, phenol red, reactive black 5, reactive brilliant violet and tropeolin 00 by more than 70% within 24 hours of incubation. Cu(II)/peroxide system can decolourize Chicago sky blue, reactive black 5, Remazol brilliant violet, poly R 478, reactive blue by more than 70% in 24 hours. Cu(II)/peroxide system was tested for its ability to decolourize industrial effluents and compared to other pyridine and succinic acid containing Cu(II) systems.

Keywords
Synthetic dye
industrial effluent
decolourization
discharge
Conflict of interest
The authors declare they have no competing interests.
References

Buschmann, H.J., Jonas, C. and E. Schollmeyer (1996). The selective removal of dyes from waste water. European Water Pollution Control, 6: 21.

Feigelson, L., Muszkat, L., Bir, L. and K.A. Muszkat (2000). Dye photo-enhancement of TiO2-photocatalyzed degrada- tion of organic pollutants: the organobromine herbicide bromacil. Water Science and Technology, 42: 275.

Gabriel, J., Shah, V., Nesmerak, K., Baldrian, P. and F. Nerud(2000). Degradation of polycyclic aromatic hydrocarbons by the copper (II)-hydrogen peroxide system. Folia Microbiology, 45: 573.

Juang, R.S., Wu, F.C. and R.L. Tseng (1997). Ability of activated clay for the adsorption of dyes from aqueous solution. Environmental Technology, 18: 525.

Lee, C.K., Low, K.S. and P.Y. Gan (1999). Removal of some organic dyes by acid-treated spent bleaching earth. Environmental Technology, 20: 99.

Microbics Corp. (1992). Microtox Manual, Vol. 2. Detailed Protocols, Carlsbad, CA.

Nansheng, D., Feng, W., Fan, L. and L. Zan (1997). Photodegradation of dyes in aqueous solutions containing Fe( III )-oxalato complex. Chemosphere, 35: 2697.

Nerud, F., Baldrian, P., Gabriel, J. and D. Ogbeifun (2001). Decolorization of synthetic dyes by the Fenton reagent and the Cu/pyridine/H2O2 system. Chemosphere, 47: 957.

Salem, I.A. (2000). Kinetics of the oxidative color removal and degradation of bromophenol blue with hydrogen peroxide catalyzed by copper(II)-supported alumina and zirconia. Applied Catalysis B: Environmental, 28: 153.

Shah, V., Verma, P., Stopka, P., Gabriel, J., Baldrian, P. and F. Nerud (2003). Decolourization of dyes with copper (II)/ organic acid/Hydrogen peroxide system. Applied Catalysis B: Environmental, 46: 287.

Spadaro, J.T., Isabelle, L. and V. Renganathan (1994). Hydroxyl radical mediated degradation of azo dyes: Evidence for benzene generation. Environmental Science and Technology, 28: 1389-1393.

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Asian Journal of Water, Environment and Pollution, Electronic ISSN: 1875-8568 Print ISSN: 0972-9860, Published by AccScience Publishing