Box-Behnken Design of Experiments in the Adsorption of Anionic Dyes on the Bio Polymer Chitosan

The adsorption of anionic dye acid Orange 10 and acid Orange 51 on chitosan, a food processing industrial bio polymeric waste was studied. Box-Behnken model and analysis of variance (ANOVA) have been applied to the experimental adsorption studies. Response surface method with three levels of variances namely pH (6.7, 7.4, 9.2),
particle size (0.100, 0.175 and 0.250 mm) and temperature (30, 45 and 60°C) were used in the identification of significant effects and interaction in the batch adsorption studies. A second order polynomial regression model has been developed using experimental data. From the results it was found that the selected variables as a strong effect on adsorption and also the experimental values were in good agreement with predicted values with the correlation coefficient value in the range of » 0.99.
Allen, S.J., McKay, G. and K.Y.H. Khader (1989b). Equilibrium Absorption isotherms for Basic dye onto lignite. J.Chem. Technol. Biotechnol., 45: 291-298.
Annadurai, G. and M.R.V. Krishnan (1996). Absorption of basic dye using Chitin.Indian J.Env.Prot., 16(6):444-449. Annadurai, G., Sivakumar,T. and S. Rajesh Babu (2000). Photo catalysis decolorization of Congo red over ZnO powder using Box-Behnken design of experiments, Bio-Process Engg., 23: 167-173.
Box, G.E.P. and D.W. Behnken (1960). Three-level design for the study of quantitative variables. Technometrics., 2: 445-475.
Box, G.E.P. and I.S. Hunter (1957). Multifactor experimental design for explaining response surfaces. Ann.Math.Statist.,28: 195-241.
Deo, N. and Manzool Ali (1993 a). Dye adsorption by a new 496-508.
Jose, Aracil (1987). Use of factorial design of experiments in the determination of adsorption equilibrium constants Methyl iodide on charcoals. J.Chem. Technol. Biotechnol.,38: 143-151.
Kpat, A., Rokshi, S.K. and T. Panda (1996). Optimization of carbon and nitrogen sources in the medium and environ- mental factors for enhanced production of chitinase by trichoderma horzianum. Bioprocess Engg., 15: 13-20.
McKay, G. (1982). Adsorption of dyestuffs from aqueous solutions with activated carbon equilibrium and batch contact time studies. J.Chem.Technol. Bio Technol., 32: 759-772.
Weber, W.J. and R.K. Chakravarthi (1974). Pore and solid diffusion modules for fixed bed adsorbent. J. Am. Inst. Chem. Engg., 22: 228-238.
Weeter, O.W. and A.G. Hodgson (1977). Dye waste water treatment. 32nd industrial waste conference, Lafayette, Proceedings, 1-9.